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Challenges in Analysis of Natural Surfactants in the Oil Sands Processing Water

  • Author / Creator
    Ma, Yuan
  • Two major kinds of natural surfactants are released during oil sands extraction: carboxylic acids (naphthenic acids) and sulfonic acids. In this study, commercial surfactants were used as standards to establish the suitable analytical methods with optimized experimental and instrumental parameters. High performance liquid chromatography (HPLC) was utilized in the work to separate individual surfactants in the mixture. For their identification and quantification, naphthenic acids were evaluated by electrospray ionization mass spectrometry (ESI ‒ MS), while sulfonic acids were done by evaporative light scattering (ELS). The developed methods were then extended to the analysis of natural surfactant in oil sands process and tailings water.

  • Subjects / Keywords
  • Graduation date
    2012-11
  • Type of Item
    Thesis
  • Degree
    Master of Science
  • DOI
    https://doi.org/10.7939/R37H4Q
  • License
    This thesis is made available by the University of Alberta Libraries with permission of the copyright owner solely for non-commercial purposes. This thesis, or any portion thereof, may not otherwise be copied or reproduced without the written consent of the copyright owner, except to the extent permitted by Canadian copyright law.
  • Language
    English
  • Institution
    University of Alberta
  • Degree level
    Master's
  • Department
    • Department of Chemical and Materials Engineering
  • Supervisor / co-supervisor and their department(s)
    • Xu, Zhenghe (Chemical and Materials Engineering)
  • Examining committee members and their departments
    • Liu, Qingxia (Chemical and Materials Engineering)
    • Szymanski, Jozef (Civil and Environmental Engineering)
    • Xu, Zhenghe (Chemical and Materials Engineering)
    • Zeng, Hongbo (Chemical and Materials Engineering)