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A ruthenium-carbamato-complex derived from a siloxylated amine and carbon dioxide for the oxidative a-cyanation of aromatic and cyclic tertiary amines
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- Author(s) / Creator(s)
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The ruthenium carbamate complex derived from 3-trimethoxysilyl-1-
propyl amine and carbon dioxide was found to be a novel catalyst for
the oxidative cyanation of aromatic and cyclic tertiary amines to
corresponding a-amino nitriles in high to excellent yields by using
hydrogen peroxide and molecular oxygen as enviro-economic
oxidants. The developed protocol suggested an efficient alternative
for recycling carbon dioxide. -
- Date created
- 2013-10-09
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- Subjects / Keywords
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- Type of Item
- Article (Published)