Recovery of Cyclohexane from Oil Sands Gangue Using Microwave: Influence of Fine Particles

• Author / Creator

  Hussein, Tasneem

• The extraction of bitumen from oil sands using non-aqueous extraction (NAE) techniques has the
  potential to replace currently used water-based extraction techniques. High bitumen recovery rates, lower
  freshwater requirements, and elimination of afterward tailing ponds are all advantages of non-aqueous
  extraction. Other benefits include a significant reduction in energy use and greenhouse gas emissions
  related to global warming and ozone depletion.
  Using an organic solvent, bitumen is extracted from the oil sands ore during the nonaqueous extraction
  process, leaving behind a mixture of coarse and fine solids containing water, residual bitumen, and
  residual solvent (cyclohexane in this study), or “gangue”. Regardless of its numerous advantages, a
  significant environmental and economical drawback of the NAE method is the removal of solvent from
  the gangue post extraction.
  A well-defined procedure to control the gangue composition was necessary in order to accurately analyze
  the impact of gangue components on solvent recovery from the gangue. Reconstituted gangue samples
  were prepared to create a synthetic sample whose drying behavior represented that of the non-aqueous
  extraction gangue. The utilization of reconstituted gangue was necessary because it represented samples
  whose composition could be precisely controlled for analysis.
  This research demonstrated the effect of varying the content of fine particles at constant residual bitumen,
  water, and cyclohexane contents on the removal of cyclohexane from reconstituted gangue using two
  different solvent removal mechanisms: microwave-only in and air-drying followed by microwave. Heat
  was generated internally within the reconstituted gangue during the microwave experiment upon the
  interaction of the dipolar molecules with microwave radiation.
  iii
  For reconstituted gangue samples undergoing only microwave heating, cyclohexane required more time
  to go through phase change, regardless of fine particles content. The temperature at which cyclohexane
  underwent phase change was significantly depressed for all samples undergoing microwave heating for
  all contents of fine particles. There was no apparent difference between the duration of cyclohexane
  evaporation in samples with 10% and 20% fine particles. The time required for cyclohexane to be
  removed from the gangue becomes independent of fine particles content at increased contents of fine
  particles. The maximum temperature reached by the Soxhlet solids remained unchanged for gangue
  samples with 10 wt.% fine particles but somewhat increased upon the addition of 20 wt.% fine particles,
  relative to samples containing 0 wt.% fine particles.
  For reconstituted gangue samples undergoing air-drying prior to microwave heating, the duration at
  which cyclohexane underwent phase change reached its maximum at 10 wt.% fine particles content. This
  duration was similar for samples containing 0 wt.% and 20 wt.% fine particles. The temperature at which
  cyclohexane underwent phase change was comparable to cyclohexane’s normal boiling point for all
  contents of fine particles. The duration of cyclohexane evaporation in reconstituted gangue samples
  containing 10% and 20% fine particles was doubled and tripled, respectively, relative to reconstituted
  gangue samples containing no fine particles. The time required for cyclohexane to evaporate from the
  reconstituted gangue significantly increases at increased contents of fine particles. The average
  maximum temperature reached by the Soxhlet solids was independent of the content of fine particles.
  Finally, fine particles accelerated the recovery of cyclohexane using microwave and lowered the
  evaporation onset temperature.

• Subjects / Keywords

  • oil sands
  • non aqueous extraction
  • microwave
  • fine particles
  • gangue
  • cyclohexane

• Graduation date

  Fall 2022

• Type of Item

  Thesis

• Degree

  Master of Science

• DOI

  https://doi.org/10.7939/r3-agge-1p50

• License

  This thesis is made available by the University of Alberta Library with permission of the copyright owner solely for non-commercial purposes. This thesis, or any portion thereof, may not otherwise be copied or reproduced without the written consent of the copyright owner, except to the extent permitted by Canadian copyright law.