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Permanent link (DOI): https://doi.org/10.7939/R30K94

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Effect of Laminar Shear on the Aggregate Structure of Flocculant-dosed Kaolinite Slurries Open Access

Descriptions

Other title
Subject/Keyword
Aggregate
Oil sands Tailings
Flocculation
Reflocculation
Shearing
Non-spherical drag coefficient
Laminar flow
Shear degradation
Type of item
Thesis
Degree grantor
University of Alberta
Author or creator
Vaezi Ghobaeiyeh, Farid
Supervisor and department
Supervisor: Dr. Sean Sanders, Dept of Chemical and Materials Engineering
Co-supervisor: Dr. Jacob H. Masliyah, Dept of Chemical and Materials Engineering
Examining committee member and department
Sanders, Sean (Chemical and Materials Engineering)
Masliyah, Jacob (Chemical and Materials Engineering)
Yarranton, Harvey (Chemical and Petroleum Engineering, University of Calgary)
Buchanan, Ian (Civil and Environmental Engineering)
Kresta, Suzanne (Chemical and Materials Engineering)
Department
Department of Chemical and Materials Engineering
Specialization
Chemical Engineering
Date accepted
2013-03-27T15:59:38Z
Graduation date
2013-06
Degree
Doctor of Philosophy
Degree level
Doctoral
Abstract
The research was conducted to investigate effect of hydrodynamic conditioning on the flocculation of the oil sands fine tailings. The main focus was the effect of shearing on the structure of flocculated aggregates and the extent of reflocculation occurring upon cessation of shearing. An experimental technique was developed based on laminar tube flow. This allowed a more realistic estimation of the shear rate to which an aggregate was exposed, and direct sampling of the aggregate to minimize alteration of the aggregate structure by sampling. A combination of aggregate settling velocity and image analysis was used to determine the aggregate structural parameters, i.e. size, shape, density and fractal dimension. The laminar flow device was used to investigate the flocculation kinetics and evolution of the aggregate structure. Aggregates were formed by flocculation of kaolinite particles, as model clay, with an anionic flocculant under physicochemical conditions similar to those of oil sands tailings. Detailed statistical analysis showed that a dynamic equilibrium flocculation state was established and the formed aggregate structure was statistically reproducible. The accuracy of aggregate density and fractal dimension measurements using size and settling velocity data was improved by developing a new non-spherical drag coefficient correlation. The new correlation uses only two dimensional geometrical parameters obtained from image analysis. The correlation is applicable to the study of fluid particle dynamics for any fragile and non-spherical particles, including the type produced during the treatment and dewatering of oil sands tailings. The flocculated aggregates, with well-defined and reproducible structures, were exposed to a wide range of shear rates for different periods of time. The shearing experiments were performed using the laminar tube flow device. The results showed that shearing reduced aggregate size, increased aggregate density and compacted the structure. Also, shearing ultimately produced aggregates having more spherical shapes. Both the magnitude and duration of shearing were found to be important. The degraded aggregates could reflocculate to some degree upon cessation of shearing. The extent of reflocculation was almost independent of the shearing history and the reflocculated aggregates regained much of their original structural properties (i.e. before shearing) with a slight structural compaction. The results suggest that the controlled shearing and subsequent reflocculation can improve de-watering and consolidation properties of flocculated fine tailings.
Language
English
DOI
doi:10.7939/R30K94
Rights
Permission is hereby granted to the University of Alberta Libraries to reproduce single copies of this thesis and to lend or sell such copies for private, scholarly or scientific research purposes only. Where the thesis is converted to, or otherwise made available in digital form, the University of Alberta will advise potential users of the thesis of these terms. The author reserves all other publication and other rights in association with the copyright in the thesis and, except as herein before provided, neither the thesis nor any substantial portion thereof may be printed or otherwise reproduced in any material form whatsoever without the author's prior written permission.
Citation for previous publication
Vaezi G., F., Sanders, R.S., Masliyah, J.H., (2011). “Flocculation kinetics and aggregate structure of kaolinite mixtures in laminar tube flow”, J. Colloid and Interface Sci. 355, 96-105.

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