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Journal Articles (Chemistry)
Items in this Collection
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2015-01-01
Shao, Wenjie, Clive, Derrick L. J.
A new family of routes to substituted phenols has been developed. 2-Bromo-3- methoxycyclohex-2-en-1-ones are readily deprotonated at C-6 and the resulting anions react smoothly with a variety of electrophiles; treatment with DBU in PhMe at room temperature then results in efficient aromatization...
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Formation of meta-Substituted Phenols by Transition Metal-Free Aromatization: Use of 2-Bromocyclohex-2-en-1-ones.
Download2016-01-01
Yu, Guojun, Clive, Derrick L. J.
Addition of Grignard- or other organometallic reagents to 3-halocyclohex-2-en- 1-ones bearing an alkyl or aryl group at C-5, followed by mild acid treatment and exposure to DBU at room temperature, generates meta-substituted phenols in which the newly introduced meta substituent originates from...