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- 29Chemistry
- 23Organic compounds. Synthesis.
- 22Catalysis
- 22Metabolomics
- 21Capillary electrophoresis.
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Energy Storage Materials: Mitigating the Degradation of Alloy-based Anodes for Lithium and Sodium Ion Batteries
DownloadSpring 2023
Lithium ion batteries have become a ubiquitous technology for consumer electronics and electric vehicles. Alloying anodes, such as silicon and tin, offer large increases in volumetric energy density compared to conventional graphite anodes. However, the alloying mechanism is accompanied by an...
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Spring 2022
Nanomaterials based upon Group 14 elements (i.e., silicon and germanium) are drawing a great deal of attention from researchers since they are biocompatible and exhibit unique optical and electronic properties. Surface functionalization, which is one of the most critical aspects of nanomaterial...
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Functional Genomics of Bacterial and Fungal Biocontrol Agents for Biotechnological Applications
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Microbial-based biotechnologies were developed using combinations of functional genomics, biochemical tools, and a tripartite pine tree-beetle-fungal infection model. Several bacterial and fungal species were probed for natural product biosynthesis potential using whole genome sequencing while...
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Spring 2022
Phage display libraries bearing natural amino acids are commonly used for discovering potential therapeutic macrocycles; however, direct application of those linear peptides often leads to poor pharmacokinetics, including low serum stability, lower cell membrane permeability, and rapid renal...
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Spring 2023
Glycosylation is the enzymatic modification of biomacromolecules (proteins, etc.) with carbohydrates known as glycans. Naturally occurring in all organisms from viruses to animals, glycans have multifaceted functions in all aspects of biology. Aberrant glycosylation is often observed in diseases...
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Applications of DECIDE Quantum-Classical Dynamics: Proton Transfer and Quantum Battery Models
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The quantum-classical Liouville equation (QCLE) provides a foundation for simulating the dynamics of quantum systems coupled to classical environments. Many processes including proton-transfer reactions, electron-transfer reactions, and heat transport in molecular junctions, for example, take...
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Spring 2022
The work in this Thesis outlines the use of N-heterocyclic olefins (NHOs) as organocatalysts, as supporting ligands in palladium-catalyzed cross-coupling, and the development of anionic NHOs as ligands for main group element and transition metal centers. N-Heterocyclic olefin-hydridodiborane...
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Spring 2022
Polymer based materials have been utilized widely for applications that can be of benefit to human health and the environment. This thesis covers the general scope of polymer materials on bases of star-shaped polymer and temperature-responsive poly (N-isopropylacrylamide) (pNIPAm) microgels,...
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Functionalized Thermo-responsive Polymer Core-shell Materials for use in Controlled Dye Release, Thin-film Composite Membranes, and Water Desalination
DownloadSpring 2024
This thesis focuses on the varied applications of core-shell structured stimuli- responsive polymer materials and their applications in water treatment. The relevant background and introduction to stimuli-responsive polymers, core-shell particles and morphologies, and membrane separations systems...
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New abundant 4CzIPN-derivatized Photosensitizers and Catalysts for Photosynthetic Organic Reactions and Solar Fuels
DownloadSpring 2024
The development of artificial photosynthetic systems is a promising strategy to meet future energy demands of our society and to reverse the impact of anthropogenic CO2 in the environment. Energy conversion devices such as photoelectrochemical cells are one key component in the transition to a...