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Skip to Search Results- 15Graduate Studies and Research, Faculty of
- 15Graduate Studies and Research, Faculty of/Theses and Dissertations
- 1Chemistry, Department of
- 1Chemistry, Department of/Research Data and Materials (Chemistry)
- 1Oil Sands Research and Information Network (OSRIN)
- 1Oil Sands Research and Information Network (OSRIN)/OSRIN Technical Reports
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Spring 2020
On a perfect hydrogen-terminated Si(100)-2x1 surface, each surface silicon atom is capped with exactly one atom of hydrogen. When one of the capping hydrogen atoms is removed, the now unsatisfied orbital of the underlying silicon atom is exposed at that site. This site is better known as a...
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Observing and Manipulating Single Electrons Confined to Silicon Dangling Bond Ensembles with Non-Contact Atomic Force Microscopy
DownloadFall 2018
Non-contact atomic force microscopy (nc-AFM) is capable of inducing and resolving single-electron charge transitions of surface adsorbates. Here, these techniques are extended by studying the charge configurations of dangling bond (DB) ensembles on the hydrogen-terminated silicon surface. nc-AFM...
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Fall 2017
The elements of Group 14 show an extensive range of chemical behaviors. Lying at the boundary between metals and non-metals, some members of Group 14, namely silicon and germanium, are intermediate in their properties. These semiconductors are extremely important in science and technology. Si,...
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Spring 2017
We present the characterization of close-spaced linear dangling bond structures, or dangling bond chains, two to seven dangling bonds long, on a hydrogen terminated silicon (100)-2x1 surface using a scan- ning tunnelling microscope. Constant height differential conductance maps reveal their local...
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Fall 2017
This thesis will discuss the charge dynamics of dangling bonds (DBs) on the hydrogen terminated Si(100) surface under the effects of temperature and perturbations from local electric fields. The experimental methods are then extended towards DB chains. Electronic time resolved imaging techniques...
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Spring 2016
This thesis explores the dynamics and sensing performance of silicon quantum dot (SiQD) ensembles coupled to the whispering gallery modes (WGMs) of spherical and cylindrical microcavities. The first project investigated the possibility of observing Purcell effects in an ensemble of QDs coupled to...
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Spring 2015
This thesis focuses on the photoluminescence (PL) of free-standing silicon quan- tum dots (QDs). Large changes in the emission spectrum were found to occur when the QDs were exposed to different environments while undergoing short-wavelength laser irradiation, a phenomenon that was the main focus...
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Fall 2015
Dangling Bonds (DBs) on the silicon surface exist when a silicon atom lacks a bonding partner, resulting in a localized orbital which is not involved in any chemical bonds. On the hydrogen-terminated Si(100) surface, such DBs introduce a mid-gap state. DBs can be created on this surface by the...
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Spring 2015
This thesis is focused on the silicon-based anode materials for lithium-ion batteries (LIBs) as well as germanium-based electrode materials for sodium-ion batteries (NIBs). In our first attempt we studied electrochemical cycling stability and degradation mechanisms of silicon nanowires (SiNWs)...
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Spring 2015
Silicon nanocrystals (SiNCs) have been suggested as promising candidates for bioimaging because of their abundance, biocompatibility, and stable photoluminescent properties. However, “naked” SiNCs are insoluble in water and very reactive. As a result, NC surface functionalization is necessary to...