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- 2Shen, Jing
- 1Clive, Derrick L. J.
- 1Khosravi Hafshejani, Milad
- 1Mansouri, Ali
- 1Sun, Ho-Yan
- 1Wu, Xiaoxing
- 1Hall, Dennis G. (Chemistry)
- 1Hayes, R. E. (Department of Chemical and Materials Engineering)
- 1Hayes, Robert E. (Chemical and Materials Engineering)
- 1Semagina, Natalia (Chemical Engineering)
- 1Semagina, Natalia (Chemical and Material Engineering)
- 1Semagina, Natalia (Chemical and Materials Engineering)
Increasingly stringent environmental regulations for the sulfur content in fuels pose significant technological challenges for refineries. Current single-stage hydrodesulfurization (HDS) technologies are not efficient enough to achieve ultra-deep levels of sulfur, 10 ppmw S for transportation,...
Conversion of cycloalk-2-enones into 2-methylcycloalkane-1,3-diones - Assessment of various Tamao-Fleming procedures and mechanistic insight into the use of the Me3SiMe2Si unit.Download
Conjugate addition of Me3SiMe2SiLi to cycloalk-2-en-1-ones, ketalization, Tamao-Fleming oxidation (Bu4NF, then H2O2, KHCO3), TPAP oxidation and acid hydrolysis generates 2-methyl cycloalkane-1,3-diones. Ketalization is needed in order to prevent addition of Me3Si- to the carbonyl. The...
Breaking New Ground with the Suzuki-Miyaura Reaction: Stereoselective Cross-Couplings of 1,1-Diboronyl AlkanesDownload
Synthetic organic chemistry is an area that has seen incredible growth through the years. The level of molecular complexity that can be achieved through available synthetic methods today is remarkable. Still, as the field continues to progress, increasing focus is being placed upon the strategic...
Bimetallicity is known to provide synergistic effects and improve catalytic performance of monometallic counterparts in a variety of applications. Conventional impregnation methods for supported catalyst preparation do not allow for the control of bimetallic nanoparticle structure or size, which...
Natural-gas fuelled catalytic heaters are commonly used in heating industrial space and remote location operations. Industrial units typically contain platinum that provides methane combustion at lower temperatures than non-catalytic burning. This work aimed to find a cost-efficient alternative...
Global kinetic model for a Pt-Pd diesel oxidation catalyst (DOC) is proposed and validated. Experimental data was obtained using different concentrations of the artificial gas mixtures which were passed over a bimetallic catalyst. Previous works of Voltz , Pandya , Sola  and many others...
Selective ring opening of naphthenic molecules is a preferred reaction to increase cetane number of fuels, and it should result in products with no loss in molecular weight and longer alkyl side chains. Benzocyclopentane (indan) ring opening was studied under hydrogen atmospheric pressure at 609...