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Spring 2011
The field of plasmonics has offered the promise to combine electronics and photonics at the nanometer scale for ultrafast information processing speeds and compact integration of devices. Various plasmonic waveguide schemes were proposed with the potential to achieve switching functionalities and...
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Spring 2010
As the demand for oil and gas resources increases pipeline construction pushes further into the Arctic and sub-Arctic regions. Consequently, these buried pipelines suffer much harsh environmental and complex loading conditions. Moreover, to increase the transporting efficiency, larger size pipes...
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Fall 2017
The elements of Group 14 show an extensive range of chemical behaviors. Lying at the boundary between metals and non-metals, some members of Group 14, namely silicon and germanium, are intermediate in their properties. These semiconductors are extremely important in science and technology. Si,...
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Spring 2015
Silicon nanocrystals (SiNCs) have been suggested as promising candidates for bioimaging because of their abundance, biocompatibility, and stable photoluminescent properties. However, “naked” SiNCs are insoluble in water and very reactive. As a result, NC surface functionalization is necessary to...
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Spring 2020
On a perfect hydrogen-terminated Si(100)-2x1 surface, each surface silicon atom is capped with exactly one atom of hydrogen. When one of the capping hydrogen atoms is removed, the now unsatisfied orbital of the underlying silicon atom is exposed at that site. This site is better known as a...
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Spring 2017
We present the characterization of close-spaced linear dangling bond structures, or dangling bond chains, two to seven dangling bonds long, on a hydrogen terminated silicon (100)-2x1 surface using a scan- ning tunnelling microscope. Constant height differential conductance maps reveal their local...
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Observing and Manipulating Single Electrons Confined to Silicon Dangling Bond Ensembles with Non-Contact Atomic Force Microscopy
DownloadFall 2018
Non-contact atomic force microscopy (nc-AFM) is capable of inducing and resolving single-electron charge transitions of surface adsorbates. Here, these techniques are extended by studying the charge configurations of dangling bond (DB) ensembles on the hydrogen-terminated silicon surface. nc-AFM...
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Spring 2016
This thesis explores the dynamics and sensing performance of silicon quantum dot (SiQD) ensembles coupled to the whispering gallery modes (WGMs) of spherical and cylindrical microcavities. The first project investigated the possibility of observing Purcell effects in an ensemble of QDs coupled to...
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Interfacing Silicon-Based Quantum Dots with Proteins for Biological and Sensing Applications
DownloadFall 2020
This dissertation presents the preparation of functional bioinorganic hybrids from silicon-based quantum dots (SiQDs) and enzymes and the use of SiQDs and green fluorescent protein as ratiometric photoluminescent sensors for nerve agents. Chapter 2 discusses the preparation of water-soluble...
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Fall 2015
Dangling Bonds (DBs) on the silicon surface exist when a silicon atom lacks a bonding partner, resulting in a localized orbital which is not involved in any chemical bonds. On the hydrogen-terminated Si(100) surface, such DBs introduce a mid-gap state. DBs can be created on this surface by the...