Search
Skip to Search Results- 1Afshar, Shima
- 1Amundarain, Jesus
- 1Ansari, Nesma Nasir
- 1Berahman, Behnam
- 1Cardozo, Samuel D.
- 1Carvalho do Prado, Glaucia H
- 6Xu, Zhenghe (Chemical and Materials Engineering)
- 3Gupta, Rajender (Chemical and Materials Engineering)
- 3Liu, Qingxia (Chemical and Materials Engineering)
- 3Zeng, Hongbo (Chemical and Materials Engineering)
- 2Amirfazli, Alidad (Mechanical Engineering)
- 2Gray, Murray R. (Chemical and Materials Engineering)
-
Spring 2017
In this research, flocculation of fractionated asphaltenes was studied using dynamic light scattering (DLS). Three asphaltene fractions were obtained based on its adsorption characteristics onto calcium carbonate. The DLS results showed that the irreversibly-adsorbed asphaltenes (Irr-Ads),...
-
Pyrolysis of asphaltenes in an atmospheric entrained flow reactor: A study on gasification reactivity and properties of chars
DownloadFall 2014
Solvent deasphalting, followed by asphaltenes gasification, has been recommended as a favorable alternative to coker based upgrading processes. However, very limited work has been carried out on pyrolysis and gasification of asphaltenes, at entrained flow conditions. The present work aims at...
-
Fall 2015
The nature and structure of asphaltene nanoaggregates are frequently the subject of debate and speculation in the literature. The continental asphaltene nano-aggregate model, characterized by the presence of alkyl chains on their surface, and the archipelago nano-aggregate model, characterized...
-
Fall 2012
This thesis explored the properties of asphaltene nano-aggregates in crude oil and toluene based solutions and fouling at process furnace temperatures, and the links between these two phenomena. The link between stability of asphaltenes at ambient conditions and fouling at the conditions of a...
-
Probing Deformable Oil-Water Interfaces by Atomic Force Microscopy and Cascade Partial Coalescence Measurements
DownloadFall 2016
Phase separation of stable oil-in-water and water-in-oil emulsions poses major challenges for a variety of industries, including the petroleum industry. The stability and destabilizing of petroleum emulsions highly depend on interfacial properties such as surface/interfacial charges, interfacial...
-
Fall 2016
Athabasca oil sands contain 8 to 14% bitumen and are recovered using surface mining or steam assisted gravity drainage (SAGD). During primary upgrading of bitumen, the vacuum residuum from the distillation column is sent to the solvent de-asphalting unit where a paraffinic solvent is used to...
-
Fall 2015
Canadian oilsands bitumen contains one of the highest amounts of asphaltenes (16-20 wt %) among all crude oils. Asphaltenes are the lowest value fraction of bitumen. It differs from the other fractions of bitumen because of its insolubility in paraffinic solvents. Asphaltenes are insoluble in...
-
Fall 2012
Better definition of asphaltene structure is needed to develop new technology for upgrading, and to understand various bitumen properties. Analysis of asphaltene structure is hampered by aggregation of molecules at a length scale of 5 to 10 nm. At 300°C, the addition of aromatic solvents can...
-
Spring 2010
Most crude oils contain traces of vanadyl porphyrins within their asphaltene fraction. Although these metals are only present in trace quantities, they have a significant detrimental impact on crude oil processing units; therefore, their selective removal is highly desirable. The current work...
-
Development of Solvent Selection Criteria Based on Diffusion Rate, Mixing Quality, and Solvent Retrieval for Optimal Heavy-Oil and Bitumen Recovery at Different Temperatures
DownloadFall 2015
Heavy-oil and bitumen recovery requires high recovery factors to offset the extreme high cost of the process. Attention has been given to solvent injection for this purpose and it has been observed that high recoveries are achievable when combined with steam injection. Heavier (“liquid”) solvents...