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Skip to Search Results- 33Mass-spectrometry
- 24Chemistry
- 23Organic compounds. Synthesis.
- 22Metabolomics
- 21Capillary electrophoresis.
- 21Catalysis
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Fall 2012
This dissertation describes some advances that were made in the field of paramagnetic first-row transition metal complexes. Two independent topics will be discussed. The first topic that will be discussed is the preparation and reactivity of titanacylobutene complexes. Initially, the Stryker...
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Tools and Methodologies for The Rapid Determination and Transfer of Thermodynamic Parameters used in the Prediction of Gas Chromatographic and Two Dimensional Comprehensive Gas Chromatographic Retention Times
DownloadFall 2014
Three parameter thermodynamic predictive models have been shown previously to provide superior accuracy in the prediction of gas chromatographic retention times in comparison to other forms of modelling such as retention indices. However, these models suffer from the need for extensive...
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Fall 2017
Chapter 1 describes the total synthesis of (+)-ipalbidine. The indolizidine core structure was formed by use of an unusual 6-exo-trigonal radical cyclization as a key step. I started from the chiral pool using L-proline and obtained ipalbidine with an ee of >99.6%. Chapter 2 describes synthetic...