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Permanent link (DOI): https://doi.org/10.7939/R30C4ST3W

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Two Dimensional Modelling of Volatile Organic Compounds Adsorption in a Fixed Bed Adsorber Open Access

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Other title
Subject/Keyword
2D modeling
Volatile organic compounds
competitive adsorption
adsorption
Type of item
Thesis
Degree grantor
University of Alberta
Author or creator
Tefera,Dereje Tamiru
Supervisor and department
Dr. Zaher Hashisho , Department of Civil and Environmental engineering
Examining committee member and department
Dr. Steven Kuznicki, Department of Chemical and Materials Engineering
Dr. Zaher Hashisho, Department of Civil and Environmental Engineering
Dr. Leonidas Perez Estrada, Department of Civil and Environmental Engineering
Department
Department of Civil and Environmental Engineering
Specialization
Environmental Engineering
Date accepted
2013-09-26T20:37:16Z
Graduation date
2013-11
Degree
Master of Science
Degree level
Master's
Abstract
In this research two-dimensional mathematical models were developed to study adsorption of single component volatile organic compounds (VOCs) and competitive adsorption of n-component mixtures of VOCs from dilute gas streams in a fixed-bed adsorber. The models consist of the macroscopic mass, energy and momentum conservation equations and isotherm equations. Langmuir isotherm was used for single component VOC adsorption, while a new multicomponent isotherm model was derived to predict adsorption equilibria of VOCs mixture from single component isotherm data. The models were validated with experiments wherein deviation between measured and modeled data was quantified using the mean absolute relative error (MARE). The single component adsorption model predicted the breakthrough curves of the tested VOCs (acetone, benzene, toluene and 1, 2, 4-trimethylbenzene as well as the pressure drop and temperature during benzene adsorption with MRAE of 2.6, 11.8, and 0.8%, respectively. The model also showed very good sensitivity to the changes in operations variables such as temperature and superficial velocity of the carrier gas, channeling, and adsorbent particle size. The competitive adsorption model predicted the breakthrough profiles of binary and eight-component VOCs mixtures with 13 and 12%, MRAE respectively while that of the adsorbed amounts was 1 and 2%, respectively. These results indicate the accuracy of the models to simulate a fixed bed adsorber and their potential to be used for enhancing absorber design and optimization.
Language
English
DOI
doi:10.7939/R30C4ST3W
Rights
Permission is hereby granted to the University of Alberta Libraries to reproduce single copies of this thesis and to lend or sell such copies for private, scholarly or scientific research purposes only. Where the thesis is converted to, or otherwise made available in digital form, the University of Alberta will advise potential users of the thesis of these terms. The author reserves all other publication and other rights in association with the copyright in the thesis and, except as herein before provided, neither the thesis nor any substantial portion thereof may be printed or otherwise reproduced in any material form whatsoever without the author's prior written permission.
Citation for previous publication
 http://pubs.acs.org/doi/abs/10.1021/es402369u
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