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Predissociation processes in N22+, O22+, and NO2+, studied by ion kinetic energy spectroscopy Open Access

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Author or creator
Curtis, Jonathan M.
Boyd, Robert K
Additional contributors
Subject/Keyword
Predissociation
Mass Spectrometers
Type of item
Journal Article (Published)
Language
English
Place
Time
Description
Experimental values of kinetic energy release T, for predissociation processes of diatomic di‐cations N2+ 2, O2+ 2, and NO2 + have been obtained using techniques of ion‐kinetic‐energy spectroscopy on a double‐focusing mass spectrometer. Both unimolecular and collision‐induced processes were studied. As a result, the present data confirm earlier work but include additional transitions not reported previously. Values of T obtained by entirely different technqiues are shown to be consistent with the present work when differences in energy resolution and experimental time window are considered. Attempts to correlate all available information on these diatomic di‐cations (Auger, double‐charge‐transfer and kinetic‐energy loss spectra, as well as appearance energy measurements) are hampered by lack of high‐level a p r i o r i calculations of the potential curves.
Date created
1984
DOI
doi:10.7939/R3MK65N7J
License information
© 1984 American Institute of Physics
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Citation for previous publication
Curtis, J. M., & Boyd, R. K. (1984). Predissociation processes in N22+, O22+, and NO2+, studied by ion kinetic energy spectroscopy. Journal of Chemical Physics, 81, 2991-3001.  http://dx.doi.org/10.1063/1.448051

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