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Permanent link (DOI): https://doi.org/10.7939/R3348GW4K

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Two-Dimensional Modeling of the Effect of Relative Humidity on Volatile Organic Compounds Adsorption in a Fixed Bed Adsorber Open Access

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Other title
Subject/Keyword
modeling
relative humidity
activated carbon
volatile organic compounds
competitive adsorption
Type of item
Thesis
Degree grantor
University of Alberta
Author or creator
Laskar, Imranul I
Supervisor and department
Hashisho, Zaher (Civil and Environmental Engineering)
Examining committee member and department
Rajendran, Arvind (Chemical and Materials Engineering)
Buchanan, Ian (Civil and Environmental Engineering)
Department
Department of Civil and Environmental Engineering
Specialization
Environmental Engineering
Date accepted
2017-09-18T15:15:30Z
Graduation date
2017-11:Fall 2017
Degree
Master of Science
Degree level
Master's
Abstract
Water vapor can affect adsorption of volatile organic compound (VOC) onto activated carbon. In this research, a two-dimensional heterogenous computational fluid dynamics model was developed and validated to understand the mechanism and kinetics during competitive adsorption between VOC and water vapor in a beaded activated carbon (BAC) fixed-bed adsorber. The model comprised of a VOC-water vapor multicomponent competitive adsorption isotherm and governing transport phenomena equations. The multicomponent competitive adsorption isotherm was based on Manes method, which requires only single-component adsorption isotherms of adsorbates as inputs. Consequently, a modified Dubinin-Radushkevich (MDR) isotherm equation and Qi-Hay-Rood (QHR) isotherm equation were used to describe the pure single-component adsorption equilibrium of VOC (type I) and water vapor (type V), respectively. The MDR and QHR isotherm equations fitted the experimental data of pure VOC adsorption and water vapor adsorption on BAC with an overall r2 value of 0.998 and 0.999 respectively. The governing transport phenomena component of the model consists of macroscopic mass, momentum, and energy conversation equations. The model predicted the competitive adsorption isotherms, breakthrough and bed temperature profiles of selected VOCs (2-propanol, acetone, toluene, n-butanol, 1,2,4-trimethylbenzene) with a mean relative absolute error (MRAE) of 3.6%, 15.4% and 2.2% respectively. Sensitivity analysis was also conducted to test the robustness of the model in detecting the impact of relative humidity (RH) on VOC adsorption with change in adsorption temperature and inlet adsorbate concentration; and an overall MRAE of 6.6% was observed between the experimental and simulated results. The model, hence, can be used for optimizing adsorber design and operating conditions to minimize the impact of RH during adsorption of contaminants from gas streams.
Language
English
DOI
doi:10.7939/R3348GW4K
Rights
This thesis is made available by the University of Alberta Libraries with permission of the copyright owner solely for the purpose of private, scholarly or scientific research. This thesis, or any portion thereof, may not otherwise be copied or reproduced without the written consent of the copyright owner, except to the extent permitted by Canadian copyright law.
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