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Permanent link (DOI): https://doi.org/10.7939/R36D5PK4K

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Elemental impurities, defects and carbon isotopes in mantle diamond Open Access

Descriptions

Other title
Subject/Keyword
diamond
carbon isotopes
trace elements
micro-diamond
FTIR
Type of item
Thesis
Degree grantor
University of Alberta
Author or creator
Melton, Greg L
Supervisor and department
Stachel, Thomas (Earth and Atmospheric Sciences)
Examining committee member and department
Navon, Oded (Earth Science Institute, The Heberew University in Jerusalem)
Chacko, Tom (Earth and Atmospheric Sciences)
Muehlenbachs, Karlis (Earth and Atmospheric Sciences)
Luth, Robert (Earth and Atmospheric Sciences)
Department
Department of Earth and Atmospheric Sciences
Specialization

Date accepted
2013-08-26T14:54:14Z
Graduation date
2013-11
Degree
Doctor of Philosophy
Degree level
Doctoral
Abstract
Monocrystalline gem-quality diamonds from Akwatia, Ghana and De Beers Pool, South Africa have trace-element concentrations ranging from ppt to ppm levels, but mostly are below the limit of quantification. CeN/EuN (1–6; N = chondrite normalized) and CeN/TiN (0.6 to 12) indicate mildly elevated LREE/MREE and variable LREE/Ti. Syngenetic garnet inclusions indicate that the diamond growth medium must have been highly enriched in LREE, with CeN/EuN and CeN/TiN from 9 to 370 and 10 to 3400, respectively. One sample, G103, has trace-element characteristics that closely resemble a carbonatitic fluid. The remaining samples show discrepancies in trace-element ratios between these diamond and inclusion-based fluid/melt compositions is inconsistent with the generalized interpretation that trace impurities in gem diamond represent trapped inclusions of the diamond-forming fluid/melt. Model mixtures of submicroscopic inclusions of common peridotitic and metasomatic phases fail to mimic expected modal relationships for peridotitic sources. Additionally, the calculated inclusion abundances in these models would affect sample transparency, which is not observed. Trace-element patterns for most of the studied gem diamonds are not a direct representation of the diamond growth medium. Gem-quality micro-diamonds from the Panda kimberlite (Ekati, Canada) have δ13C values that are on average 1.3‰ higher than macro-diamonds from the same pipe. This documents either distinct diamond-forming fluids, fractionation process, or growth histories for these two populations. A broad trend to more 13C enriched compositions with decreasing mantle residence temperature (proxy for decreasing depth) is interpreted to reflect diamond formation from a carbonate-bearing metasomatic fluid/melt that isotopically evolves as it percolates upward through the compositionally layered Central Slave cratonic lithosphere. The linear relationship between platelet peak area and NB concentration that defines “regular”, non-cuboid diamonds is evaluated with a world-wide database of FTIR diamond data. This relationship is expressed as I(B’) = 0.61NB and can be projected with confidence to at least ~550 at. ppm NB. This database also shows that maximum hydrogen-related IR absorbance (3107 cm-1 center) correlates with increasing NB concentrations, implying a relationship between IR-active hydrogen at 3107 cm-1 and the aggregation process that forms B-centers in diamond.
Language
English
DOI
doi:10.7939/R36D5PK4K
Rights
Permission is hereby granted to the University of Alberta Libraries to reproduce single copies of this thesis and to lend or sell such copies for private, scholarly or scientific research purposes only. Where the thesis is converted to, or otherwise made available in digital form, the University of Alberta will advise potential users of the thesis of these terms. The author reserves all other publication and other rights in association with the copyright in the thesis and, except as herein before provided, neither the thesis nor any substantial portion thereof may be printed or otherwise reproduced in any material form whatsoever without the author's prior written permission.
Citation for previous publication
Melton, G.L., McNeill, J., Stachel, T., Pearson, D.G. and Harris, J.W., 2012, Trace- elements in gem diamond from Akwatia, Ghana and De Beers Pool, South Africa. Chemical Geology, v 314-317, p. 1-8.Melton, G.L., Stachel, T., Stern, R.A., Carlson, J., Harris, J.W., Infrared spectral and carbon isotopic characteristics of micro- and macro- diamonds from the Panda kimberlite (Central Slave Craton, Canada), 2013, Lithos, v 177, p 110-119.

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File title: Figure 1.1.���Map of southern Africa showing the location of Kimberley, South Africa. Shaded region indicates extent of the Kaapvaal craton (simplified from de Wit et al., 1992).
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